Zhan, Yanling published the artcileElectrochemical Oxidative C-H Cyanation of Quinoxalin-2(1H)-ones with TMSCN, Recommanded Product: 1,3-Dimethoxybenzene, the main research area is quinoxalinone trimethylsilyl cyanide buffer regioselective electrochem oxidative cyanation; cyanated quinoxalinone preparation.
Both quinoxalin-2(1H)-ones and nitriles are valuable organic compounds, and it is an interesting task to introduce cyano into quinoxalin-2(1H)-ones. Herein a regioselective C-H cyanation of quinoxalin-2(1H)-ones was developed with a nucleophilic cyano source TMSCN under electrochem. oxidative conditions. This process allowed the synthesis of C3 cyanated quinoxalin-2(1H)-ones, I (R1 = H, 7-Cl, 7-Br, 6,7-di-Me, etc.; R2 = H, Me, Et, allyl, Ph, Bn, etc.) in moderate to excellent yields in the absence of transition-metal catalysts and organic hydroperoxides.
European Journal of Organic Chemistry published new progress about Cyanation (Oxidative). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Recommanded Product: 1,3-Dimethoxybenzene.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem