In a broader sense, the term isoquinoline is used to make reference to isoquinoline derivatives. 1-Benzylisoquinoline is the structural backbone in naturally occurring alkaloids including papaverine. 1532-97-4, formula is C9H6BrN, Name is 4-Bromoisoquinoline. The isoquinoline ring in these natural compound derives from the aromatic amino acid tyrosine. Quality Control of 1532-97-4.
Chen, Ya-Jing;Lei, Tao;Hu, Hui-Lan;Wu, Hao-Lin;Zhou, Shuai;Li, Xu-Bing;Chen, Bin;Tung, Chen-Ho;Wu, Li-Zhu research published 《 Tandem photoelectrochemical and photoredox catalysis for efficient and selective aryl halides functionalization by solar energy》, the research content is summarized as follows. Solar energy conversion is the most important chem. transformation for green and sustainable society. Represented herein is a coupled catalytic strategy for efficient, selective, and energy-saving organic transformations, i.e., a coupled photoelectrochem./photoredox setting with Sb2(S,Se)3 as a photocathode and N,N-bis(2,6-diisopropylphenyl)perylene-3,4,9,10-bis(dicarboximide) (PDI) as a photocatalyst shows full-solar-spectrum response extending visible and near-IR (Vis-NIR) light to 1,060 nm. At -0.84 V vs. SCE, the Vis-NIR photoexcited electron from Sb2(S,Se)3 reduces PDI to PDI·-. Then, the second photoexcitation by Vis light creates higher reducing PDI·-t (-1.86 V vs. SCE) for reduction of unactivated aryl halides. The resultant aryl radicals are applied for C-C, C-P, and C-B bond-forming reactions with excellent chemoselectivity and efficacy under external sacrificial agent-free conditions. This strategy not only utilizes full solar spectrum and surmounts the limited light absorption of photocatalysis, but also overcomes the high biased potential issue in electrocatalysis.
1532-97-4, 4-Bromoisoquinoline, also known as 4-Bromoisoquinoline, is a useful research compound. Its molecular formula is C9H6BrN and its molecular weight is 208.05 g/mol. The purity is usually 95%.
4-Bromoisoquinoline is an aryl halide that can be used in the cross-coupling reaction with other aryl halides. It has been shown to have anticancer activity and to inhibit the growth of tumour cell lines in vitro. This compound is also efficient for inhibiting leukemia cells. 4-Bromoisoquinoline has been shown to have an inhibitory effect on cancer cells through the inhibition of DNA synthesis and RNA transcription, as well as by inducing apoptosis. The mechanism of action may be due to its ability to bind to aromatic hydrocarbons and halides, which leads to thermodynamic changes and vibrational energy transfer., Quality Control of 1532-97-4
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem