Gaykar, Rahul N. published the artcileTransition-Metal-Free Thioamination of Arynes Using Sulfenamides, HPLC of Formula: 5961-59-1, the main research area is sulfanylaniline preparation thioamination aryne sulfenamide; transition metal free insertion aryne vortioxetine preparation.
The insertion of arynes into the S-N σ-bond of sulfenamides allowing the synthesis of o-sulfanylaniline derivatives with reasonable functional group compatibility is presented. The aryne generated from 2-(trimethylsilyl)aryl triflates using CsF in DME was the key for the success of this transition-metal-free thioamination reaction, which involves new C-N and C-S bond formations in a single step under mild conditions. Moreover, the synthetic potential of this method was demonstrated by the synthesis of the antidepressant drug vortioxetine.
Organic Letters published new progress about Amination (thio-). 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, HPLC of Formula: 5961-59-1.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem