Guo, Wei published the artcilePhotodriven Photocatalyst/Metal-Free Direct C-C/C-N Bond Formation: Synthesis of Indoles via EDA Complexes, Related Products of isoquinoline, the main research area is alkylindoledicarboxylate preparation; photochem aerobic oxidative cycloaddition acetylenedicarboxylate alkylaniline; charge transfer complex methylaniline acetylenedicarboxylate evidence radical mechanism.
Under LED UV irradiation, N-alkylanilines such as N-methylaniline underwent aerobic oxidative cycloaddition reactions with di-Me and di-Et acetylenedicarboxylates mediated by Et3N and C4F9I in MeCN to yield N-alkylindoledicarboxylates such as I without added photocatalysts or metals. The 1:1 complex of N-methylaniline and di-Et acetylenedicarboxylate was detected by NMR, and intermediates in the reaction were observed by mass spectrometry; the reaction was inhibited by radical inhibitors.
Journal of Organic Chemistry published new progress about Charge transfer complexes Role: PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, Related Products of isoquinoline.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem