Jia, Shikun published the artcileRhodium-Catalyzed Formal C-O Insertion in Carbene/Alkyne Metathesis Reactions: Synthesis of 3-Substituted 3H-Indol-3-ols, Related Products of isoquinoline, the main research area is indolol synthesis rhodium catalyzed insertion carbene alkyne metathesis.
An efficient and novel rhodium-catalyzed formal C-O insertion reaction of alkyne-tethered diazo compounds for the synthesis of 3H-indol-3-ols is described. A type of donor/donor rhodium carbene generated in situ via a carbene/alkyne metathesis (CAM) process is the key intermediate and terminates in a unique transformation different from donor/acceptor carbenoids. In addition, 18O-labeling experiments indicate that intramol. oxygen-atom transfer from the amide group to the carbon-carbon triple bond occurs during this transformation.
Organic Letters published new progress about Carbene complexes Role: CAT (Catalyst Use), PEP (Physical, Engineering or Chemical Process), RCT (Reactant), SPN (Synthetic Preparation), USES (Uses), PROC (Process), RACT (Reactant or Reagent), PREP (Preparation) (donor/donor rhodium carbene generated in situ). 104-01-8 belongs to class isoquinoline, name is 4-Methoxyphenylacetic acid, and the molecular formula is C9H10O3, Related Products of isoquinoline.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem