Liu, Peng published the artcileN-Methylation of Amines with Methanol in the Presence of Carbonate Salt Catalyzed by a Metal-Ligand Bifunctional Ruthenium Catalyst [(p-cymene)Ru(2,2′-bpyO)(H2O)], Synthetic Route of 5961-59-1, the main research area is sulfonamide methanol cesium carbonate ruthenium catalyst methylation green chem; methylsulfonamide preparation; amine methanol cesium carbonate ruthenium catalyst methylation green chem; methylamine preparation.
A ruthenium complex [(p-cymene)Ru(2,2′-bpyO)(H2O)] was found to be a general and efficient catalyst for the N-methylation of amines with methanol in the presence of carbonate salt. Moreover,a series of sensitive substituents such as nitro, ester, cyano and vinyl groups were tolerated under present conditions. It was confirmed that OH units in the ligand were crucial for the catalytic activity. Notably, this research exhibited the potential of metal-ligand bifunctional ruthenium catalysts for the hydrogen auto-transfer process.
Journal of Organic Chemistry published new progress about Amines Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, Synthetic Route of 5961-59-1.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem