Liu, Wei published the artcileMesoionic Carbene (MIC)-Catalyzed H/D Exchange at Formyl Groups, Name: 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, the main research area is aldehyde triazolylidene catalyst deuteration; imine triazolylidene catalyst deuteration.
Investigation of the reaction of aldehydes with 1,2,3-triazolylidenes has revealed the reversible formation of Breslow intermediates and the inhibition of the condensation steps in methanol solvent. 1,2,3-Triazolylidenes catalyzed the H/D exchange of aryl, alkenyl and alkyl aldehydes in high yields and deuterium incorporation levels using deuterated methanol as an affordable D source. The unique properties of these mesoionic carbenes (MICs) enabled a streamlined preparation of deuterated synthetic intermediates and pharmacophores that are highly valuable as mechanistic and metabolic probes.
Chem published new progress about Deuteration. 1205-17-0 belongs to class isoquinoline, name is 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, and the molecular formula is C11H12O3, Name: 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem