Wang, Baolu published the artcileA Borane Lewis Acid in the Secondary Coordination Sphere of a Ni(II) Imido Imparts Distinct C-H Activation Selectivity, Name: 1,3-Dimethoxybenzene, the main research area is aromatic compound carbon hydrogen bond activation kinetics nickel imide; crystal structure boryldiphosphine nickel imido metallacyclic complex.
Two borane-functionalized bidentate phosphine ligands that vary in tether length were prepared to examine cooperative metal-substrate interactions. Ni(0) complexes react with aryl azides at low temperatures to form structurally unusual κ2-(N,N)-N3Ar adducts. Warming these adducts affords products of N2 extrusion and in one case, a Ni-imido compound that is capped by the appended borane. Reactions with 1-azidoadamantane (AdN3) provide a distinct outcome, where a proposed Ni imido intermediate activates the sp2 C-H bonds of arenes, even in the presence of benzylic C-H sites. Combined exptl. and computational mechanistic studies demonstrate that the unique reactivity is a consequence of Lewis-acid-induced polarization of the Ni-NR bond, potentially providing a synthetic strategy for chemoselective reaction engineering.
Journal of the American Chemical Society published new progress about Aryl azides Role: PEP (Physical, Engineering or Chemical Process), PRP (Properties), RCT (Reactant), PROC (Process), RACT (Reactant or Reagent). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Name: 1,3-Dimethoxybenzene.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem