Al-Ahmary, Khairia M. published the artcileThermodynamic study and spectroscopic analysis of a charge-transfer complex between 3,5-diamino-1,2,4-triazole and 6-methyl-1,3,5-triazine-2,4-diamine with chloranilic acid, Application In Synthesis of 1455-77-2, the main research area is diamino triazole methyl triazine diamine chloranilic acid spectroscopic analysis.
Studying of charge-transfer (CT) and proton transfer interactions is essential due to their important role in many biol. field and industrial applications. The current work will add more information’s about the nature of interaction between 3,5-diamino-1,2,4-triazole (DAT) and 6-methyl-1,3,5-triazine-2,4-diamine (MTDA) with 3,6-dichloro-2,5-dihydroxy-p-benzoquinone (chloranilic acid CLA) which was studied spectrophotometrically in Ethanol (EtOH) and Methanol (MeOH) solvents at different temperatures The mol. composition of the formed complexes was studied by applying continuous variation and spectrophotometric titration methods and found to be 1:1 charge transfer complex for both Complex (DAT:CLA) and (MTDA:CLA) which are produced. Min.-Maximum absorbance’s method has been applied to calculate the formation constant KCT and mol. extinction coefficient (ε); they recorded high values confirming high stability of the produced complexes. Oscillator strength (f), transition dipole moment (μ), ionization potential (IP) and dissociation energy (W) of the formed CT-complexes were also determined and evaluated; they showed solvent dependency. It is concluded that the formation constant (KCT) of the complexes is found to depend on the nature of both electron acceptor and donors and on the polarity of solvents.
Open Journal of Physical Chemistry published new progress about Chemical potential. 1455-77-2 belongs to class isoquinoline, name is 3,5-Diamino-1,2,4-triazole, and the molecular formula is C2H5N5, Application In Synthesis of 1455-77-2.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem