Genre, Caroline published the artcileAdditive-free selective methylation of secondary amines with formic acid over a Pd/In2O3 catalyst, Safety of 4-Methoxy-N-methylaniline, the main research area is methylamine preparation; secondary amine formic acid methylation palladium catalyst.
Formic acid is used as the sole carbon and hydrogen source in the methylation of aromatic and aliphatic amines R1NHR2 (R1 = Ph, Bn, cyclohexyl, propan-2-yl, etc.; R2 = H, Me, cyclohexyl, Ph, propan-2-yl; R1R2 = -CH2CH2OCH2CH2-) to methylamines R1N(CH3)R2. The reaction proceeds via a formylation/transfer hydrogenation pathway over a solid Pd/In2O3 catalyst without the need for any additive.
Catalysis Science & Technology published new progress about Methylation. 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, Safety of 4-Methoxy-N-methylaniline.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem