Giofre, Sabrina published the artcileEnantio- and Regioselective Palladium(II)-Catalyzed Dioxygenation of (Aza-)Alkenols, Name: 4-Methoxyphenylacetic acid, the main research area is morpholine enantioselective regioselective preparation; allyl azaalkenol oxycarbonylphenyl iodane palladium catalyst dioxygenation intamol cyclization; tetrahydro pyran enantioselective regioselective preparation; allylalkenol oxycarbonylphenyl iodane palladium catalyst dioxygenation intamol cyclization; Pd catalysis; alkene difunctionalizations; alkenols; dioxygenation; enantioselectivity; hypervalent iodine.
An oxidative Pd-catalyzed intra-intermol. dioxygenation of (aza-)alkenols were reported, with total regioselectivity. To study the stereoselectivity, different chiral ligands as well as different hypervalent-iodine compounds was compared. In particular, by using a C-6 modified pyridinyl-oxazoline (Pyox) ligand and hypervalent iodine bearing an aromatic ring, an excellent enantio- and diastereoselectivity was achieved.
Angewandte Chemie, International Edition published new progress about Aliphatic alcohols Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 104-01-8 belongs to class isoquinoline, name is 4-Methoxyphenylacetic acid, and the molecular formula is C9H10O3, Name: 4-Methoxyphenylacetic acid.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem