He, Zhen published the artcileThe Interrupted Pummerer Reaction in a Sulfoxide-Catalyzed Oxidative Coupling of 2-Naphthols, Recommanded Product: 4-Methoxyphenylacetic acid, the main research area is interrupted Pummerer reaction sulfoxide catalyzed oxidative coupling naphthol; nigerone isonigerone synthesis; BINOLs; Pummerer reaction; metal-free catalysis; oxidative coupling; sulfoxide.
A benzothiophene S-oxide catalyst, generated in situ by sulfur oxidation with H2O2, mediates the oxidative coupling of 2-naphthols. Key to the catalytic process is the capture and inversion of reactivity of a 2-naphthol partner, using an interrupted Pummerer reaction of an unusual benzothiophene S-oxide, followed by subsequent coupling with a second partner. The new catalytic manifold has been showcased in the synthesis of the bioactive natural products, (±)-nigerone (I) and (±)-isonigerone (II). Although Pummerer reactions are used widely, their application in catalysis is rare, and our approach represents a new catalytic manifold for metal-free C-C bond formation.
Angewandte Chemie, International Edition published new progress about Aromatization (as driving force for catalyst regeneration). 104-01-8 belongs to class isoquinoline, name is 4-Methoxyphenylacetic acid, and the molecular formula is C9H10O3, Recommanded Product: 4-Methoxyphenylacetic acid.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem