Li, Yufei published the artcileVisible-Light-Induced Photocatalyst-Free Radical Trifluoromethylation, Recommanded Product: 4-Methoxy-N-methylaniline, the main research area is heteroarene trifluoromethyl thianthrenium salt trifluoromethylation; trifluoromethyl heteroarene preparation; hydrazone trifluoromethyl thianthrenium salt trifluoromethylation; trifluoromethylhydrazone preparation; acrylamide trifluoromethyl thianthrenium salt trifluoromethylation; trifluoroethylindolinone preparation.
An attractive, versatile, and operationally simple, visible-light-induced, transition-metal-free, photocatalyst-free, and oxidant-free trifluoromethylation has been demonstrated. Triflic anhydride (Tf2O), being inexpensive and readily available, was chosen as the radical trifluoromethyl source. Thianthrene was used as a recyclable Tf2O-activating reagent, and a high-yielding and scalable trifluoromethylation reaction was achieved. D. functional theory and mechanistic studies showed that a free radical homolytic process excited by visible light is involved in this reaction, generating a key trifluoromethyl radical intermediate.
Organic Letters published new progress about Anilines Role: RCT (Reactant), RACT (Reactant or Reagent). 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, Recommanded Product: 4-Methoxy-N-methylaniline.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem