Liu, Mingyang’s team published research in Proceedings of the National Academy of Sciences of the United States of America in 2022-05-24 | CAS: 151-10-0

Proceedings of the National Academy of Sciences of the United States of America published new progress about Chlorination. 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Formula: C8H10O2.

Liu, Mingyang published the artcileChlorination of arenes via the degradation of toxic chlorophenols, Formula: C8H10O2, the main research area is arene chlorination toxic chlorophenol degradation; aryl chloride; chlorophenol pollutant; decontamination; isofunctional reaction.

Aryl chlorides are among the most versatile synthetic precursors, and yet inexpensive and benign chlorination techniques to produce them are underdeveloped. Authors propose a process to generate aryl chlorides by chloro-group transfer from chlorophenol pollutants to arenes during their mineralization, catalyzed by Cu(NO3)2/NaNO3 under aerobic conditions. A wide range of arene substrates have been chlorinated using this process. Mechanistic studies show that the Cu catalyst acts in cooperation with NOx species generated from the decomposition of NaNO3 to regulate the formation of chlorine radicals that mediate the chlorination of arenes together with the mineralization of chlorophenol. The selective formation of aryl chlorides with the concomitant degradation of toxic chlorophenol pollutants represents a new approach in environmental pollutant detoxication. A reduction in the use of traditional chlorination reagents provides another (indirect) benefit of this procedure.

Proceedings of the National Academy of Sciences of the United States of America published new progress about Chlorination. 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Formula: C8H10O2.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem