Senthamarai, Thirusangumurugan published the artcileUltra-small cobalt nanoparticles from molecularly-defined Co-salen complexes for catalytic synthesis of amines, Recommanded Product: 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, the main research area is amine preparation; carbonyl compound ammonia cobalt salen nanocatalyst; aldehyde amine cobalt salen nanocatalyst.
The synthesis of in situ generated cobalt nanoparticles from molecularly defined complex cobalt(II)-N,N’-bis(salicylidene)-1,2-phenylenediamine as efficient and selective catalysts for reductive amination reactions. In the presence of ammonia and hydrogen, cobalt-salen complexes such as cobalt(II)-N,N’-bis(salicylidene)-1,2-phenylenediamine produce ultra-small (2-4 nm) cobalt-nanoparticles embedded in a carbon-nitrogen framework. The resulting materials constitute stable, reusable and magnetically separable catalysts, which enable the synthesis of linear and branched benzylic, heterocyclic and aliphatic primary amines RCH(R1)NH2 [R = Ph, pyridin-3-yl, 4-tert-butylcyclohexyl, etc.; R1 = H, Me, n-Bu, Bn; RR1 = -(CH2)7-] from carbonyl compounds RC(O)R1 and ammonia. The isolated nanoparticles also represent excellent catalysts for the synthesis of primary, secondary as well as tertiary amines including biol. relevant N-Me amines R2CH2N(R3)(R4) (R2 = Ph, pyridin-3-yl, n-heptyl, etc.; R3 = Ph, n-hexyl, cyclopentyl, etc.; R4 = H, Me).
Chemical Science published new progress about Carbonyl compounds (organic) Role: RCT (Reactant), RACT (Reactant or Reagent). 1205-17-0 belongs to class isoquinoline, name is 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, and the molecular formula is C11H12O3, Recommanded Product: 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem