Yang, Guoqiang published the artcileMigrative Carbofluorination of Saturated Amides Enabled by Pd-Based Dyotropic Rearrangement, Formula: C9H10O3, the main research area is functionalized amide preparation; saturated amide dyotropic rearrangement migrative carbofluorination palladium catalyst.
Herein, a palladium-catalyzed migrative carbofluorination of saturated amides enabled by the activation of both the C(sp3)-H and the Cquaternary-Cσ bonds was reported for the synthesis of functionalized amides. In this transformation, the α-quaternary carbon of Weinreb amides was converted to α-tertiary fluoride with concurrent migration of an aryl or an amido group from the α- to β-carbon. DFT calculations indicate that the dyotropic rearrangement proceeds through an unusual anti-selective [2.1.0] bicyclic transition state.
Journal of the American Chemical Society published new progress about Fluorination. 104-01-8 belongs to class isoquinoline, name is 4-Methoxyphenylacetic acid, and the molecular formula is C9H10O3, Formula: C9H10O3.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem