Yang, Wei published the artcileEnantioselective Formal Vinylogous N-H Insertion of Secondary Aliphatic Amines Catalyzed by a High-Spin Cobalt(II) Complex, Recommanded Product: 4-Methoxy-N-methylaniline, the main research area is diazo pyrazolyl butenone secondary amine cobalt catalyst insertion reaction; amino pyrazolylbutenone preparation enantioselective diastereoselective regioselective.
Highly γ-selective and enantioselective insertion into N-H bonds of aliphatic or aromatic secondary amines with vinyl substituted α-diazo pyrazoleamides using a high-spin chiral N,N’-dioxide/cobalt(II) complex catalyst. The method afforded a wide variety of valuable optically active Z- and E-type vinyl γ-amino amides. Calculation revealed a spin state change from the quartet cobalt(II) complex to a doublet Co(II)-carbene species for facile Z-selective and enantioselective nucleophilic addition
Journal of the American Chemical Society published new progress about Diazo compounds, amido Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, Recommanded Product: 4-Methoxy-N-methylaniline.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem