Yu, Rongrong published the artcileRegio-, Chemo-, and Enantioselective Ni-Catalyzed Hydrocyanation of 1,3-Dienes, Formula: C11H12O3, the main research area is nitrile preparation regioselective chemoselective enantioselective; diene hydrocyanation nickel catalyst.
A regio-, chemo-, and enantioselective nickel-catalyzed hydrocyanation of 1,3-dienes e.g., 1-[(1E)-buta-1,3-dien-1-yl]-4-fluorobenzene is reported. The key to the success of this asym. transformation is the use of a specific multichiral diphosphite ligand. In addition to aryl-substituted 1,3-dienes, highly challenging aliphatic 1,3-diene substrates can also be preferentially converted to the corresponding 1,2-adducts e.g., (2R,3E)-4-(4-fluorophenyl)-2-methylbut-3-enenitrile in decent yields with the highest enantioselectivities to date.
Organic Letters published new progress about Chemoselectivity. 1205-17-0 belongs to class isoquinoline, name is 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, and the molecular formula is C11H12O3, Formula: C11H12O3.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem