Ding, Wei published the artcileSite-selective aromatic C-H λ3-iodanation with a cyclic iodine(III) electrophile in solution and solid phases, SDS of cas: 151-10-0, the main research area is arylbenziodoxole site selective preparation; arene benziodoxole triflate site selective aromatic iodanation.
An efficient and site-selective aromatic C-H λ3-iodanation reaction was achieved using benziodoxole triflate (BXT) as an electrophile under room temperature conditions. The reaction tolerated a variety of electron-rich arenes and heteroarenes to afford the corresponding arylbenziodoxoles I [R = 4-OMeC6H4, 2,4-di-MeC6H3, 2-thienyl, etc.] in moderate to good yields. The reaction could also be performed mechanochem. by grinding a mixture of solid arenes and BXT under solvent-free conditions. The arylbenziodoxoles could be used for various C-C and C-heteroatom bond formations and are also amenable to further modification by electrophilic halogenation. DFT calculations suggested that the present reaction proceeded via a concerted λ3-iodanation-deprotonation transition state, where the triflate anion acts as an internal base.
Chemical Science published new progress about Alkadiynes Role: SPN (Synthetic Preparation), PREP (Preparation) (unsym.). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, SDS of cas: 151-10-0.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem