Lu, Shang-Yuan published the artcilePyridinylidenaminophosphines as Versatile Organocatalysts for CO2 Transformations into Value-Added Chemicals, Recommanded Product: 4-Methoxy-N-methylaniline, the main research area is cyclic carbonate formyl amine preparation pyridinylidenaminophosphine catalyst.
The carboxylative cyclization of propargylic alcs. with CO2 was developed employing pyridinylidenaminophosphines (PYA-Ps) as organocatalyts for the first time. Moderate to good yields of α-methylene cyclic carbonates were obtained with excellent chemo- and stereo-selectivity. D. functional theory (DFT) calculations reveal that the catalytic reaction tends to proceed via the pyridinylidenaminophosphines-mediated basic ionic pair mechanism, and the intramol. cyclization should be the rate determining step. Furthermore, the catalytic diversity of PYA-Ps was investigated for the chem. transformations of CO2 to functionalized cyclic carbonates and N-formylated amines.
Asian Journal of Organic Chemistry published new progress about Alcohols, propargyl Role: RCT (Reactant), RACT (Reactant or Reagent). 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, Recommanded Product: 4-Methoxy-N-methylaniline.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem