Luo, Shu-Zheng’s team published research in Advanced Synthesis & Catalysis in 2020-07-17 | CAS: 151-10-0

Advanced Synthesis & Catalysis published new progress about Alkanes Role: SPN (Synthetic Preparation), PREP (Preparation) (diaryl). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Formula: C8H10O2.

Luo, Shu-Zheng published the artcileSynthesis of Bulky 1,1-Diarylalkanes by Copper-Catalyzed 1,2-Alkylarylation of Styrenes with α-Carbonyl Alkyl Bromides and Arenes involving C-H Functionalization, Formula: C8H10O2, the main research area is diarylalkane preparation copper catalyst; styrene carbonyl alkylbromide arene alkylarylation.

A copper and silver-promoted intermol. 1,2-alkylarylation of styrenes with α-carbonyl alkyl bromides and arenes for producing highly bulky 1,1-diarylalkane derivatives I (Ar = 2,4-diOMeC6H3, 4-Me-2,6-diOMeC6H2, 2,4,6-triOMeC6H2, etc; R1 = 4-MeC6H4, 4-OEtC6H4, 4-tBuC6H4, etc; R2 = R3 = Me, F, c-Bu, etc; R4 = OMe, OEt, C6H5.) has been developed. In this transformations, two new C-C bonds were formed in a single reaction step through C-Br bond cleavage and C(sp2)-H functionalization. This protocol tolerates a variety of α-carbonyl alkyl bromides, including primary, secondary and tertiary α-bromoalkyl ketone esters.

Advanced Synthesis & Catalysis published new progress about Alkanes Role: SPN (Synthetic Preparation), PREP (Preparation) (diaryl). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Formula: C8H10O2.

Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem