Marchetti, Mauro published the artcileAqueous biphasic hydrogenations catalyzed by rhodium and iridium complexes modified with human serum albumin, SDS of cas: 1205-17-0, the main research area is biphasic hydrogenations catalysis rhodium iridium complex; catalyst human serum albumin unsaturated aldehyde.
Water soluble complexes derived from the interaction between Rh(CO)2(acac) and [Ir(COD)Cl]2, resp., with human serum albumin (HSA), were employed in the aqueous biphasic hydrogenation of α,β-unsaturated compounds as 2-cyclohexen-1-one (I), 2-butenal (V), 3-phenyl-2-propenal (IX) and 3-aryl-2-methyl-2-propenals (XIII and XVII). Both catalytic systems Rh/HSA and Ir/HSA showed to be very active in the hydrogenation of ketone I even at low temperature and hydrogen pressure; in particular, the rhodium based catalyst showed to be very selective affording exclusively cyclohexanone (II). The α,β-unsaturated aldehydes investigated required higher temperature (up to 60°) and pressure (5 MPa) to obtain good conversions. In this case Rh/HSA resulted to be more active than Ir based catalyst. In all cases both Rh/HSA and Ir/HSA were easily recycled without significant loss of activity.
Applied Catalysis, A: General published new progress about Blood serum albumins Role: CAT (Catalyst Use), USES (Uses) (human). 1205-17-0 belongs to class isoquinoline, name is 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, and the molecular formula is C11H12O3, SDS of cas: 1205-17-0.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem