Muratov, Karim published the artcileConfinement-Induced Selectivities in Gold(I) Catalysis-The Benefit of Using Bulky Tri-(ortho-biaryl)phosphine Ligands, Quality Control of 151-10-0, the main research area is crystal structure; Catalysis; Confinement; Cycloisomerization; Gold; Phosphine Ligands.
The confinement of a catalytic site is an efficient strategy to control a reaction and modulate its selectivity. In the present work, a new class of structurally simple and easily accessible bulky tri-(ortho-biaryl)phosphine ligands were accessed, and their gold(I) complexes [LAuX] [L = [2-(RC6H4)C6H4]3P, where R = 3-tBu, 3-Bu, 4-tBu, 4-C5H11; L = [2-(2-naphthyl)phenyl]3P; X = Cl, NTf2, NCMe] were prepared Their X-ray diffraction anal. and the comparative evaluation of their VBur% and G steric parameters against a series of gold complexes commonly employed in catalysis demonstrated their confined nature. Despite their notable steric congestion, these complexes exhibited remarkable catalytic activities and unusual selectivities, both in nature and level, that make them unique in the field of synthetic homogeneous gold catalysis.
Angewandte Chemie, International Edition published new progress about Alkenynes Role: RCT (Reactant), RACT (Reactant or Reagent) (derivatives). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Quality Control of 151-10-0.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem