Wang, Shuaishuai published the artcileDecarboxylative tandem C-N coupling with nitroarenes via SH2 mechanism, Recommanded Product: 4-Methoxyphenylacetic acid, the main research area is aryl tertiary amine preparation; nitroarene carboxylic acid tandem decarboxylative coupling iron catalyst photochem.
In this paper, a radical tandem C-N coupling strategy to efficiently construct aromatic tertiary amines from com. available carboxylic acids and nitroarenes was developed. A variety of aromatic tertiary amines were furnished in good yields (up to 98%) with excellent functional group compatibility under mild reaction conditions. The use of two different carboxylic acids also allowed for the concise synthesis of nonsym. aromatic tertiary amines in satisfactory yields. Mechanistic studies suggested the intermediacy of the arylamine-(TPP)Fe(III) species and might provide a possible evidence for an SH2 (bimol. homolytic substitution) pathway in the critical C-N bond formation step.
Nature Communications published new progress about Carboxylic acids Role: RCT (Reactant), RACT (Reactant or Reagent). 104-01-8 belongs to class isoquinoline, name is 4-Methoxyphenylacetic acid, and the molecular formula is C9H10O3, Recommanded Product: 4-Methoxyphenylacetic acid.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem