Xu, Chao published the artcileFeCl3-catalyzed three-component aryl-selenylation of alkenes, Category: isoquinoline, the main research area is diarylethyl arylselane preparation; alkene aromatic hydrocarbon diselenide three component selenylation iron catalyst.
FeCl3-catalyzed three-component aryl-selenylation of alkenes 4-R-C6H4CH=CH2 (R = H, F, Me, Ph, etc.) with good to excellent yields has been disclosed. This method is characterized by synthesis of complicated products 4-R-C6H4CH(Ar)CH2Se(2-R1-3-R2-4-R3C6H2) [Ar = 2,4,6-trimethoxyphenyl, 2,4-dimethoxyphenyl, 1H-indol-3-yl, etc.; R1 = H, Cl; R2 = H, Me; R3 = H, F, Cl, Br, Me, OMe, CF3] in a single-step reaction, simple operation and readily available com. reagents. Finally, a reasonable mechanism of FeCl3-catalyzed aryl-selenylation is proposed.
Tetrahedron published new progress about Aromatic hydrocarbons Role: RCT (Reactant), RACT (Reactant or Reagent). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Category: isoquinoline.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem