Doan, Son H. published the artcileA New Synthetic Pathway to Triphenylpyridines via Cascade Reactions Utilizing a New Iron-Organic Framework as a Recyclable Heterogeneous Catalyst, SDS of cas: 104-01-8, the main research area is benzenetricarboxylic acid biphenyldicarboxylic iron complex preparation thermal stability crystallinity; phenylacetic acid acetophenone ammonium acetate iron tandem aldol cyclocondensation; triphenyl pyridine preparation.
A new iron-organic framework, VNU-22 ̅{[Fe3(BTC)(BPDC)2].11.97H2O}, constructed from BTC3-, BPDC2-pillars and infinite [Fe3(CO2)7]∞rod SBU, was obtained. The VNU-22 was utilized as a heterogeneous catalyst in the synthesis of 2,4,6-triphenylpyridines via cascade reactions from acetophenones and phenylacetic acids with ammonium acetate as a nitrogen source. The VNU-22 was more active in the cascade reactions than many homogeneous and heterogeneous catalysts. The framework catalyst was recovered and reutilized without an appreciable decline in its performance. To our best knowledge, this synthetic pathway to 2,4,6-triphenylpyridines was not previously reported and would attract interests from the chem. industry.
European Journal of Organic Chemistry published new progress about Acetophenones Role: RCT (Reactant), RACT (Reactant or Reagent). 104-01-8 belongs to class isoquinoline, name is 4-Methoxyphenylacetic acid, and the molecular formula is C9H10O3, SDS of cas: 104-01-8.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem