Hazra, Susanta published the artcileReactivity of Styrenes in Micelles: Safe, Selective, and Sustainable Functionalization with Azides and Carboxylic Acids, Safety of 4-Methoxyphenylacetic acid, the main research area is azide ester preparation; styrene carboxylic acid amphiphile PS 750M mimics NBS oxyfunctionalization.
An amphiphile PS-750-M that mimics dipolar-aprotic organic solvents enables N-bromo succinimide (NBS)-mediated one-pot oxyfunctionalization of styrenes in water under mild conditions. Control experiments reveal the involvement of the radical pathway. The radical intermediate was also trapped with butylated hydroxytoluene to obtain a peroxy educt. The method is scalable without involving any operational risk. This aqueous micellar technol. for oxyfunctionalization is further applied on in situ reduction and click chem. to obtain β-azido alcs. and β-carbonyl triazoles.
ACS Sustainable Chemistry & Engineering published new progress about Azides Role: SPN (Synthetic Preparation), PREP (Preparation). 104-01-8 belongs to class isoquinoline, name is 4-Methoxyphenylacetic acid, and the molecular formula is C9H10O3, Safety of 4-Methoxyphenylacetic acid.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem