He, Feifei published the artcileSilver-Catalyzed N-H Functionalization of Aryl/Aryl Diazoalkanes with Anilines, Name: 4-Methoxy-N-methylaniline, the main research area is benzhydryl amine preparation; aniline diaryldiazoalkane insertion reaction silver catalyst.
Herein, the N-H functionalization reaction of primary and secondary anilines RNHR1 (R = H, Me, Et, Ph; R1 = Ph, 3-bromophenyl, 2H-1,3-benzodioxol-5-yl, etc.) with diaryldiazoalkanes R2C(=N2)R3 (R2 = Ph, 2-chlorophenyl, 3-nitrophenyl, etc.; R3 = Ph, 4-methoxyphenyl, 3-methylphenyl, etc.) using simple AgPF6 as catalyst was reported. Broad applicability in the reaction of diaryldiazoalkanes with different anilines (31 examples, up to 97% yield) was demonstrated. Furthermore, a possible reaction mechanism for the N-H functionalization was proposed.
Organic Letters published new progress about Amines Role: SPN (Synthetic Preparation), PREP (Preparation). 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, Name: 4-Methoxy-N-methylaniline.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem