Kim, Junghwa published the artcileIntermolecular Markovnikov-Selective Hydroacylation of Olefins Catalyzed by a Cationic Ruthenium-Hydride Complex, SDS of cas: 1205-17-0, the main research area is branched ketone preparation intermol Markovnikov selective hydroacylation olefin aldehyde; cationic ruthenium hydride complex catalyzed hydroacylation regioselective ketone preparation; aldehyde; alkene; branched ketone; hydroacylation; ruthenium catalyst.
The cationic Ru-H complex was found to be an effective catalyst for the intermol. hydroacylation of aryl-substituted olefins with aldehydes to form branched ketone products. The preliminary kinetic and spectroscopic studies elucidated a ruthenium-acyl complex as the key intermediate species. The catalytic method directly afforded branched ketone products in a highly regioselective manner while tolerating a number of heteroatom functional groups.
ACS Catalysis published new progress about Aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 1205-17-0 belongs to class isoquinoline, name is 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, and the molecular formula is C11H12O3, SDS of cas: 1205-17-0.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem