Maazaoui, Radhouan published the artcileDomino Methylenation/Hydrogenation of Aldehydes and Ketones by Combining Matsubara’s Reagent and Wilkinson’s Catalyst, Safety of 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, the main research area is domino methylenation hydrogenation aldehyde ketone Matsubara reagent Wilkinson catalyst.
The methylenation/hydrogenation cascade reaction of aldehydes or ketones through a domino process involving two ensuing steps in a single pot is realized. The compatibility of Matsubara’s reagent and Wilkinson’s complex give a combination that allows, under dihydrogen, the transformation of a carbonyl function into a Me group. This new method is suitable to introduce an Et motif from aromatic and aliphatic aldehydes with total chemoselectivity and total retention of α-stereochem. purity. The developed procedure is also extended to the introduction of Me groups from ketones.
European Journal of Organic Chemistry published new progress about Aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 1205-17-0 belongs to class isoquinoline, name is 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, and the molecular formula is C11H12O3, Safety of 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem