Wang, Jixiao published the artcileUnsupported Nanoporous Palladium Catalyst for N-Formylation of Amines Using CO2 as a Sustainable C1 Source, COA of Formula: C8H11NO, the main research area is formamide green preparation; amine carbon dioxide formylation nanoporous palladium catalyst.
An efficient heterogeneous catalytic system for the synthesis of aryl formamides R1N(C(O)H)R2 [R1 = Ph, 4-MeC6H4, 2-MeOC6H4, etc.; R2 = H, Me, Bn, etc.; R1 = R2 = Ph, Bn, Cy, etc.] via N-formylation of amines using CO2 as a sustainable C1 source was developed using unsupported nanoporous palladium (PdNPore). The PdNPore-catalyzed N-formylation of amines and CO2 with hydrosilane proceeded smoothly under mild reaction conditions to yield formamides in satisfactory to excellent yields. No palladium leached from PdNPore during the hydrogenation reaction. Moreover, the catalyst was easily recovered and reused without any loss of catalytic activity. This study was the first to demonstrate that PdNPore catalyzed CO2 conversion to form C-N bond, which enriches the reaction types of CO2 conversion catalyzed by PdNPore catalyst.
Asian Journal of Organic Chemistry published new progress about Amines Role: RCT (Reactant), RACT (Reactant or Reagent). 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, COA of Formula: C8H11NO.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem