Zhang, Yu-Lan published the artcileVinyl Sulfonium Salts as the Radical Acceptor for Metal-Free Decarboxylative Alkenylation, Application In Synthesis of 104-01-8, the main research area is vinyl sulfonium salt radical acceptor decarboxylative alkenylation.
Vinyl sulfonium salts typically act as an electrophilic Michael acceptor, thus initiating many tandem cyclization reactions. Herein, we disclosed the novel reactivity of vinyl sulfonium salts as a radical acceptor. Using redox-active ester as an alkyl radical precursor, metal-free decarboxylative alkenylation with vinyl sulfonium salts was realized using eosin Y as a photocatalyst. This process features a broad substrate scope and tolerates a broad range of primary, secondary, tertiary carboxylic acids.
Organic Letters published new progress about Alkenylation catalysts, stereoselective (photochem.). 104-01-8 belongs to class isoquinoline, name is 4-Methoxyphenylacetic acid, and the molecular formula is C9H10O3, Application In Synthesis of 104-01-8.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem