Hong, Seung Youn published the artcileChemoselective Primary Amination of Aryl Boronic Acids by PIII/PV=O-Catalysis: Synthetic Capture of the Transient Nef Intermediate HNO, Computed Properties of 371766-08-4, the publication is Journal of the American Chemical Society (2022), 144(20), 8902-8907, database is CAplus and MEDLINE.
A catalytic approach to intercept the transient HNO for a chemoselective primary amination of arylboronic acids was reported. A phosphetane-based catalyst operating within PIII/PV=O redox cycling was shown to capture HNO, generated in situ by Nef decomposition of 2-nitropropane, to selectively install the primary amino group at aryl Csp2 centers. The method furnished versatile primary arylamines from arylboronic acid substrates with the preservation of otherwise reactive functional groups.
Journal of the American Chemical Society published new progress about 371766-08-4. 371766-08-4 belongs to isoquinoline, auxiliary class Isoquinoline,Boronic acid and ester,Boronic Acids,Boronic acid and ester, name is Isoquinolin-5-ylboronic acid, and the molecular formula is C9H8BNO2, Computed Properties of 371766-08-4.
Referemce:
https://en.wikipedia.org/wiki/Isoquinoline,
Isoquinoline | C9H7N – PubChem