Hunter, Arianne C. published the artcileRhodium/Gold Dual Catalysis in Carbene sp2 C-H Functionalization/Conia-ene Cascade for the Stereoselective Synthesis of Diverse Spirocarbocycles, Recommanded Product: 4-Methoxy-N-methylaniline, the main research area is spirocarbocycle preparation diastereoselective; diazo compound Conia ene cascade reaction rhodium gold catalyst.
A Rh(II)/Au(I) catalyzed carbene cascade approach for the stereoselective synthesis of diverse spirocarbocycles, e.g., I is described. The cascade reaction involves a rhodium carbene initiated sp2 C-H functionalization followed by a gold catalyzed Conia-ene cyclization. The cascade reaction accommodates a variety of aryl substituents as well as ring sizes and proceeds with high diastereoselectivity providing access to diverse spirocarbocycles, e.g., I.
Advanced Synthesis & Catalysis published new progress about C-H bond activation. 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, Recommanded Product: 4-Methoxy-N-methylaniline.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem