Ma, Yun published the artcileReactions of Sodium Diisopropylamide: Liquid-Phase and Solid-Liquid Phase-Transfer Catalysis by N,N,N’,N”,N”-Pentamethyldiethylenetriamine, Product Details of C8H10O2, the main research area is Liquid Phase Solid Liquid PhaseTransfer Catalysis pentamethyldiethylenetriamine; Reactions Sodium Diisopropylamide.
Sodium diisopropylamide (NaDA) in dimethylethylamine (DMEA) and DMEA-hydrocarbon mixtures with added N,N,N’,N”,N”-pentamethyldiethylene triamine (PMDTA) reacts with alkyl halides, epoxides, hydrazones, arenes, alkenes, and allyl ethers. Comparisons of PMDTA with N,N,N’,N’-tetramethylethylenediamine (TMEDA) accompanied by detailed rate and computational studies reveal the importance of the trifunctionality and κ2-κ3 hemilability. Rate studies show exclusively monomer-based reactions of 2-bromooctane, cyclooctene oxide, and dimethylresorcinol. Catalysis with 10 mol % PMDTA shows up to >30-fold accelerations (kcat > 300) with no evidence of inhibition over 10 turnovers. Solid-liquid phase-transfer catalysis (SLPTC) is explored as a means to optimize the catalysis as well as explore the merits of heterogeneous reaction conditions.
Journal of the American Chemical Society published new progress about Dehydrohalogenation. 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Product Details of C8H10O2.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem