Asymmetric Allylboration of Cyclic Imines and Applications to Alkaloid Synthesis was written by Wu, T. Robert;Chong, J. Michael. And the article was included in Journal of the American Chemical Society in 2006.Synthetic Route of C11H13NO2 This article mentions the following:
Treatment of cyclic imines with 3,3′-disubstituted binaphthol modified allylboronates provides the expected allylated products in good yields and with high stereoselectivities (91-99% ee). The products may be readily transformed into several naturally occurring alkaloids. In the experiment, the researchers used many compounds, for example, 6,7-Dimethoxy-3,4-dihydroisoquinoline (cas: 3382-18-1Synthetic Route of C11H13NO2).
6,7-Dimethoxy-3,4-dihydroisoquinoline (cas: 3382-18-1) belongs to isoquinoline derivatives. Being an analog of pyridine, isoquinoline is a weak base, with a pKa of 5.14. Other industrial applications include their use as corrosion inhibitors, preservatives, and as solvents for resins and terpenes.Synthetic Route of C11H13NO2
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem