Miao, Hongjie; Bai, Xuguan; Wang, Lele; Yu, Junhui; Bu, Zhanwei; Wang, Qilin published the artcile< Diastereoselective construction of cage-like and bridged azaheterocycles through dearomative maximization of the reactive sites of azaarenes>, Product Details of C10H9NO, the main research area is cage like bridged azaheterocycle preparation diastereoselective; pyridinium quinolinium isoquinolinium diazapentadienium salt dearomatization.
A highly diastereoselective multicomponent dearomative multifunctionalization of N-alkyl activated azaarenes with 1,5-diazapentadienium salts has been developed, which not only represented a significant advance in maximum utilization of the reactive sites of azaarenes, but also provided a convenient and robust approach to access structurally rigid and synthetically challenging cage-like and bridged azaheterocycles. As an important complement, author also realized the dearomative multi-functionalization of N-aryl azaarenes through an in situ activation strategy. Moreover, the workup-directed selective tri- and bi-functionalization of isoquinolinium salts have been accomplished.
Organic Chemistry Frontiers published new progress about Bridged heterocyclic compounds Role: SPN (Synthetic Preparation), PREP (Preparation). 90806-58-9 belongs to class isoquinoline, and the molecular formula is C10H9NO, Product Details of C10H9NO.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem