Huang, Cheng; Wang, Jing-Hao; Qiao, Jia; Fan, Xiu-Wei; Chen, Bin; Tung, Chen-Ho; Wu, Li-Zhu published the artcile< Direct Arylation of Unactivated Alkanes with Heteroarenes by Visible-Light Catalysis>, Synthetic Route of 90806-58-9, the main research area is alkane heteroarene arylation iridium visible light; alkylheteroarene preparation; iridium visible light arylation catalyst.
The functionalization of aliphatic C-H bonds is both a major challenge and a desirable goal in organic synthesis. Here, a successful arylation of unactivated alkanes with heteroarenes by using iridium polypyridyl complexes as the photocatalyst and persulfate as the HAT catalyst precursor under visible-light irradiation, is described. This reaction features good functional group tolerance and broad scope with regard to both alkane and heteroarene substrates (37 examples), which allows direct access to alkyl-substituted N-heteroarenes, a key structural motif in natural products and bioactive mols.
Journal of Organic Chemistry published new progress about Alkanes Role: RCT (Reactant), RACT (Reactant or Reagent). 90806-58-9 belongs to class isoquinoline, and the molecular formula is C10H9NO, Synthetic Route of 90806-58-9.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem