Shi, Cuiying published the artcileRoom-Temperature C-H Bromination and Iodination with Sodium Bromide and Sodium Iodide Using N-Fluorobenzenesulfonimide as an Oxidant, SDS of cas: 151-10-0, the main research area is quinoline fluorobenzenesulfonimide regioselective oxidative halogenation green chem; benzene fluorobenzenesulfonimide regioselective oxidative halogenation green chem.
A transition-metal-free electrophilic bromination and iodination of arene through C-H cleavage at room temperature was developed in excellent to quant. yields with broad arene scope and good regioselectivity, in which environment-benign and readily available sodium halides, NaBr or NaI, were employed as halogen sources in accompany with N-fluorobenzenesulfonimide (NFSI) as an oxidant. Studies was demonstrated that, in this air- and moisture-resistant scalable halogenation under mild conditions, the oxidant NFSI was reduced to dibenzenesulfonimide which usually serves as the starting material for the preparation of NFSI, rendering this facile and versatile protocol promising potentials for future applications in organic synthesis.
ChemistrySelect published new progress about Bromination, regioselective (oxidative). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, SDS of cas: 151-10-0.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem