Xu, Yan published the artcilePhotochemical, Nickel-Catalyzed C(sp3)-C(sp3) Reductive Cross-Coupling of α-Silylated Alkyl Electrophiles and Allylic Sulfones, Name: 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, the main research area is nickel catalyzed reductive cross coupling silylated alkyl bromide allylsulfone; homoallylic silane preparation.
A Ni-catalyzed C(sp3)-C(sp3) cross-electrophile coupling between α-silylated alkyl bromides and an allylic sulfone is reported. Instead of a metal as the stoichiometric reductant, this photochem. reductive process relies on a Hantzsch ester but does not require an exogenous photocatalyst. The role of the silyl group in the α-position and its stabilizing effect on the assumed C-centered radical intermediate is demonstrated. The functional-group tolerance is excellent, allowing for the synthesis of various homoallylic silanes.
ACS Catalysis published new progress about Bromoalkanes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 1205-17-0 belongs to class isoquinoline, name is 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, and the molecular formula is C11H12O3, Name: 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem