Feng, Yunxia published the artcileIntermolecular alkene arylcyanation using BnSCN as a cyanide source via a reductive strategy: access to 3,3-disubstituted oxindoles, Application of 4-Methoxyphenylacetic acid, the main research area is oxindole preparation; alkene benzyl thiocyanate reductive intermol arylcyanation nickel catalyst.
Herein, a nickel-catalyzed two-component reductive arylcyanation of aryl (pseudo)halide tethered alkenes using benzyl thiocyanate as the cyanide source via C-S bond activation is developed. Using this protocol, a wide scope of 3,3-disubstituted oxindoles bearing all-carbon quaternary stereocenters are accessible in moderate to excellent yields. The preliminary mechanistic investigations reveal that a Ni(I)/Ni(III) process might be involved in the mechanism.
Organic Chemistry Frontiers published new progress about Cyanation. 104-01-8 belongs to class isoquinoline, name is 4-Methoxyphenylacetic acid, and the molecular formula is C9H10O3, Application of 4-Methoxyphenylacetic acid.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem