Huang, Zijun published the artcileMn-Catalyzed Selective Double and Mono-N-Formylation and N-Methylation of Amines by using CO2, COA of Formula: C8H11NO, the main research area is formamide preparation; aryl amine carbon dioxide formylation manganese catalyst; methyl amine preparation; carbon dioxide amine methylation manganese catalyst; amines; carbon dioxide; formylation; homogeneous catalysis; manganese.
The catalytic formylation and methylation of amines (cyclohexanamine, morpholine, piperazine, 1-naphthylamine, etc.) represent convenient and successful protocols for selective CO2 utilization as a C1 building block. This study represents the first example of selective catalytic double N-formylation of aryl amines RNH2 [R = 4-FC6H4, 2-H3CC6H4, naphthalen-1-yl, etc.] by using a dinuclear Mn complex in the presence of phenylsilane. This robust system also allows for selective formylation and methylation of amines under a range of conditions.
ChemSusChem published new progress about Formamides Role: SPN (Synthetic Preparation), PREP (Preparation). 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, COA of Formula: C8H11NO.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem