Jud, Wolfgang published the artcileElectrochemical α-Arylation of Ketones via Anodic Oxidation of in situ Generated Silyl Enol Ethers, Name: 1,3-Dimethoxybenzene, the main research area is aryl ketone electrochem arylation arene; aralkyl ketone preparation.
An electrochem. procedure for the α-arylation of ketones has been developed. The method is based on the generation and one-pot anodic oxidation of silyl enol ethers in the presence of an arene. This strategy avoids isolation of the silyl enol intermediate and the utilization of external supporting electrolytes. Intermol. arylations, which had not been reported so far, are possible when electron-rich arenes are utilized as coupling partners. The method has been demonstrated for a wide variety of aryl ketones and activated arenes in moderate to good yields (up to 69%). Mechanistic insights and a theor. rationale that explained the ketone α-arylation vs. dimerization selectivity are also presented.
Journal of Organic Chemistry published new progress about Aralkyl ketones Role: SPN (Synthetic Preparation), PREP (Preparation). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Name: 1,3-Dimethoxybenzene.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem