Gangu, Kranthi Kumar published the artcileCatalytic activity of supra molecular self-assembled Nickel(II) coordination complex in synthesis of indeno-pyrimidine derivatives, SDS of cas: 86-51-1, the main research area is crystal structure nickel bipyridine pyridinedicarboxylate preparation catalyst indenopyrimidine green; aldehyde indanedione reaction guanidinium catalyst green nickel bipyridine pyridinedicarboxylate.
A supra mol. self-assembled Ni(II) coordination complex, formulated as [Ni2(2,6-pydc)2(μ-4,4’bpy)(H2O)4]·4H2O (2,6-pydcH2 = pyridine-2,6-dicarboxylic acid, 4,4’bpy = 4,4′-bipyridine) was synthesized under hydrothermal condition and characterized by single crystal x-ray diffraction, elemental anal., FTIR, powder x-ray diffraction, and thermo gravimetric anal. Single crystal x-ray diffraction anal. reveals that the complex crystallizes in the monoclinic space group P21/c with a 10.5237(6), b 20.1966(10), c 7.2366(4) Å, β = 106.96(1°) and displays a 3-dimensional supramol. network through H bond and C-H···π, C-O···π interactions. Ni(II) metal species in the structure possess coordinately unsaturated centers, which exhibited viable catalytic properties in the synthesis of eight different indeno-pyrimidine derivatives through 1-pot reaction involving benzaldehydes, indane-1,3-dione and guanidinium chloride in a green approach. With the reaction achieved in 15 min time interval in EtOH in excellent yields (87-98%), plus the good recyclability (up to 6 times) provides advantage to this complex in heterogeneous catalysis.
Polyhedron published new progress about Benzaldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 86-51-1 belongs to class isoquinoline, name is 2,3-Dimethoxybenzaldehyde, and the molecular formula is C9H10O3, SDS of cas: 86-51-1.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem