Wu, Shanxuan published the artcileRecyclable Oxofluorovanadate-Catalyzed Formylation of Amines by Reductive Functionalization of CO2 with Hydrosilanes, SDS of cas: 5961-59-1, the main research area is potassium vanadium fluoride oxide catalyst preparation recyclable; amine carbon dioxide phenylsilane formylation; amide preparation formylation; amides; carbon dioxide; fluorides; heterogeneous catalysis; silanes.
An efficient method was developed for the reductive amination of CO2 by using readily available and recyclable oxofluorovanadates as catalysts. Various amines were transformed into the desired N-formylated products in moderate to excellent yields at room temperature in the presence of phenylsilane. Mechanistic studies based on in situ IR spectroscopy suggest a reaction pathway initiated through F-Si interactions. The activated phenylsilane allows for CO2 insertion to produce phenylsilyl formate, which undergoes attack by the amine to generate the target product.
ChemSusChem published new progress about Amides Role: SPN (Synthetic Preparation), PREP (Preparation). 5961-59-1 belongs to class isoquinoline, name is 4-Methoxy-N-methylaniline, and the molecular formula is C8H11NO, SDS of cas: 5961-59-1.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem