Faulkner, Adele published the artcilePalladium catalyzed cyclizations of oxime esters with 1,1-disubstituted alkenes: synthesis of α,α-disubstituted dihydropyrroles and studies towards an asymmetric protocol, Application In Synthesis of 21834-92-4, the main research area is palladium catalyst cyclization oxime ester alkene alpha asym; dihydropyrrole preparation.
The authors report efficient Pd-catalyzed cyclizations of oxime esters with 1,1-disubstituted alkenes as the basis of a general entry to α,α-disubstituted pyrrolidine derivatives, e.g. I [R1 = Ph, 2-naphthyl, 4-pyridinyl, etc.]. The authors also demonstrate that catalytic asym. variants of this chem. are feasible by employing a suitable chiral ligand.
Chemical Communications (Cambridge, United Kingdom) published new progress about Alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 21834-92-4 belongs to class isoquinoline, name is 5-Methyl-2-phenylhex-2-enal, and the molecular formula is C13H16O, Application In Synthesis of 21834-92-4.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem