Berlot, Jean published the artcileAminoquinolines. XI. Decomposition of tertiary 4-aminoquinolines and of related amines by hydrobromic acid in aqueous solution. Influence of the nature of the ring and of the hydrocarbon chain, Formula: C10H10N2, the publication is Bulletin de la Societe Chimique de France (1973), 3175-8, database is CAplus.
Tertiary 4-aminoquinolines I [R = R1 = Me, Pr, allyl, Ph, CH2Ph, (CH2)2Ph, (CH2)3Ph; R2 = Me, R3 = H; R-R3 = Me; R = R1 = Pr, R2 = R3 = Me; R = R1 = Me, CH2Ph, R2 = R3 = H] were completely dealkylated to the corresponding secondary amines by boiling dilute HBr. When R â?R1 the shorter radical was eliminated preferentially. The reaction was general for N-heterocyclic amines in which the amine was ortho or para to the ring N. Other amines R4NR5R6 (R4 = 2-quinolyl, 3-quinolyl, 5-quinolyl, 4-pyridyl, 1-naphthyl, 2-naphthyl, CH2Ph, Ph) were not dealkylated when R5 = Me and R6 = Me or Ph, but underwent partial dealkylation when R5 = R6 = CH2Ph.
Bulletin de la Societe Chimique de France published new progress about 46000-11-7. 46000-11-7 belongs to isoquinoline, auxiliary class Isoquinoline,Amine, name is N-Methylisoquinolin-1-amine, and the molecular formula is C10H10N2, Formula: C10H10N2.
Referemce:
https://en.wikipedia.org/wiki/Isoquinoline,
Isoquinoline | C9H7N – PubChem