The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Diphenyl-2-pyridylphosphine, is researched, Molecular C17H14NP, CAS is 37943-90-1, about An Electrochemically Promoted, Nickel-Catalyzed Mizoroki-Heck Reaction, the main research direction is electrochem promoted nickel catalyzed Mizoroki Heck reaction; Mizoroki Heck reaction aryl halide alkene.Electric Literature of C17H14NP.
Despite significant efforts to replace Pd-based catalysts with those of Ni, the Ni-catalyzed Mizoroki-Heck coupling of aryl halides and alkenes remains challenging. This work details the development of a Mizoroki-Heck reaction of aryl halides and a broad range of alkenes that utilizes electrochem. as a means to promote Ni-catalyzed coupling under mild conditions. Stoichiometric studies implicate low-valent Ni complexes as key intermediates in route to rapid reactions with even unactivated alkenes. As such, electrochem. is employed to readily provide the reducing potentials necessary to access these reactive intermediates and render the transformation catalytic. Cyclohexenone was found to be an unreactive substrate but a crucial additive that promotes facile electroreduction of the Ni catalyst and functionalization of other alkenes in high yields. Finally, preliminary mechanistic studies suggest that reactions proceed via an electron-chain transfer process that rapidly terminates but is reinitiated upon electroreduction
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Reference:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem