Wu, Yaxing published the artcileElectrochemical and direct C-H methylthiolation of electron-rich aromatics, Safety of 1,3-Dimethoxybenzene, the main research area is thiomethylated aromatic compound preparation; electron rich aromatic compound electrochem methylthiolation.
The electrochem.-induced C-H methylthiolation of electron-rich aromatics for the synthesis of thiomethylated aromatics ArSR [R = Me, Et, n-Pr; Ar = 4-MeOC6H4, 4-MeNHC6H4, 2-MeO-1-naphthyl, etc.] was accomplished via a three component cross-coupling strategy. Potassium thiocyanate (KSCN) as both the supporting electrolyte and sulfur source and methanol as the methylation reagent were used. This protocol was versatile for various (hetero)aromatic compounds such as aniline, anisole and indole. The reaction proceeded under mild conditions without any metal catalyst, exogenous oxidant and highly toxic sulfur reagent. Importantly, such an electrochem.-induced methylthiolated reaction could be easily scaled up with good efficiency.
Green Chemistry published new progress about Methylsulfenylation. 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Safety of 1,3-Dimethoxybenzene.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem