Xu, Guangyang published the artcileAsymmetric Arylation of Diazoesters with Anisoles Enabled by Cooperative Gold and Phosphoric Acid Catalysis, Quality Control of 151-10-0, the main research area is alpha diaryl acetate preparation enantioselective gold phosphoric acid catalyst; diazoester anisole asym arylation.
An enantioselective carbene insertion into Csp2-H bond of anisole derivatives has been accomplished using an achiral gold complex and a chiral phosphoric acid as the catalytic system, providing a novel protocol for the synthesis of chiral α,α-diaryl acetates. DFT calculations reveal the reactivity and the origin of the enantioselectivity of this reaction.
Organic Letters published new progress about Anisoles Role: RCT (Reactant), RACT (Reactant or Reagent). 151-10-0 belongs to class isoquinoline, name is 1,3-Dimethoxybenzene, and the molecular formula is C8H10O2, Quality Control of 151-10-0.
Referemce:
Isoquinoline – Wikipedia,
Isoquinoline | C9H7N – PubChem